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Context. Phosphorus (P) is considered to be one of the key elements for life, making it an important element to look for in the abundance analysis of spectra of stellar systems. Yet, only a select number of spectroscopic studies exist to estimate the phosphorus abundances and investigate its trend across a range of metallicities. This is due to the lack of good phosphorus lines in the optical wavelength region and the requirement of careful manual analysis of the blended phosphorus lines in near-infrared H-band spectra obtained with individual observations and surveys such as the Apache Point Observatory Galactic Evolution Experiment (APOGEE). Aims. Based on a consistent and systematic analysis of high-resolution, near-infrared Immersion GRating INfrared Spectrograph (IGRINS) spectra of 38 K giant stars in the Solar neighborhood, we present and investigate the phosphorus abundance trend in the metallicity range of −1.2 dex < [Fe/H] < 0.4 dex. Furthermore, we compare this trend with the available chemical evolution models to shed some light on the origin and evolution of phosphorus. Methods. We have observed full H - and K -band spectra at a spectral resolving power of R = 45 000 with IGRINS mounted on the Gemini South telescope, the Discovery Channel Telescope, and the Harlan J Smith Telescope at McDonald Observatory. Abundances were determined from spectral lines by modeling the synthetic spectrum that best matches the observed spectrum by χ 2 minimization. For this task, we used the Spectroscopy Made Easy (SME) tool in combination with one-dimensional (1D) Model Atmospheres in a Radiative and Convective Scheme (MARCS) stellar atmosphere models. The investigated sample of stars have reliable stellar parameters estimated using optical FIber-fed Echelle Spectrograph (FIES) spectra obtained in a previous study of a set of stars called Giants in the Local Disk (GILD). In order to determine the phosphorus abundances from the 16482.92 Å phosphorus line, we needed to take special care blending the CO( v = 7−4) line. With the stellar parameters known, we thus determined the C, N, and O abundances from atomic carbon and a range of nonblended molecular lines (CO, CN, and OH) which are plentiful in the H-band region of K giant stars, assuring an appropriate modeling of the blending CO( v = 7−4) line. Results. We present the [P/Fe] versus [Fe/H] trend for K giant stars in the metallicity range of −1.2 dex < [Fe/H] < 0.4 dex and enhanced phosphorus abundances for two metal-poor s-rich stars. We find that our trend matches well with the compiled literature sample of prominently dwarf stars and the limited number of giant stars. Our trend is found to be higher by ~0.05−0.1 dex compared to the theoretical chemical evolution trend resulting from the core collapse supernova (type II) of massive stars with the phosphorus yields arbitrarily increased by a factor of 2.75. Thus the enhancement factor might need to be ~0.05−0.1 dex higher to match our trend. We also find an empirically determined primary behavior for phosphorus. Furthermore, the phosphorus abundance is found to be elevated by ~0.6−0.9 dex in the two s-enriched stars compared to the theoretical chemical evolution trend. 

ABSTRACT Previous results in the literature have found the young inner-disc open cluster NGC 6705 to be mildly α-enhanced. We examined this possibility via an independent chemical abundance analysis for 11 red-giant members of NGC 6705. The analysis is based on near-infrared APOGEE spectra and relies on LTE calculations using spherical model atmospheres and radiative transfer. We find a mean cluster metallicity of $$\rm [Fe/H] = +0.13 \pm 0.04$$, indicating that NGC 6705 is metal-rich, as may be expected for a young inner-disc cluster. The mean α-element abundance relative to iron is $$\rm \langle [\alpha /Fe]\rangle =-0.03 \pm 0.05$$, which is not at odds with expectations from general Galactic abundance trends. NGC 6705 also provides important probes for studying stellar mixing, given its turn-off mass of M ∼ 3.3 M⊙. Its red giants have low 12C abundances ([12C/Fe] = −0.16) and enhanced 14N abundances ([14N/Fe] = +0.51), which are key signatures of the first dredge-up on the red giant branch. An additional signature of dredge-up was found in the Na abundances, which are enhanced by [Na/Fe] = +0.29, with a very small non-LTE correction. The 16O and Al abundances are found to be near-solar. All of the derived mixing-sensitive abundances are in agreement with stellar models of approximately 3.3 M⊙ evolving along the red giant branch and onto the red clump. As found in young open clusters with similar metallicities, NGC 6705 exhibits a mild excess in the s-process element cerium with $$\rm [Ce/Fe] = +0.13\pm 0.07$$. 

Abstract The APOGEE Open Cluster Chemical Abundances and Mapping survey is used to probe the chemical evolution of the s-process element cerium in the Galactic disk. Cerium abundances were derived from measurements of Ce ii lines in the APOGEE spectra using the Brussels Automatic Code for Characterizing High Accuracy Spectra in 218 stars belonging to 42 open clusters. Our results indicate that, in general, for ages < 4 Gyr, younger open clusters have higher [Ce/Fe] and [Ce/ α -element] ratios than older clusters. In addition, metallicity segregates open clusters in the [Ce/X]–age plane (where X can be H, Fe, or the α -elements O, Mg, Si, or Ca). These metallicity-dependent relations result in [Ce/Fe] and [Ce/ α ] ratios with ages that are not universal clocks. Radial gradients of [Ce/H] and [Ce/Fe] ratios in open clusters, binned by age, were derived for the first time, with d [Ce/H]/ d R GC being negative, while d [Ce/Fe]/ d R GC is positive. [Ce/H] and [Ce/Fe] gradients are approximately constant over time, with the [Ce/Fe] gradient becoming slightly steeper, changing by ∼+0.009 dex kpc −1 Gyr −1 . Both the [Ce/H] and [Ce/Fe] gradients are shifted to lower values of [Ce/H] and [Ce/Fe] for older open clusters. The chemical pattern of Ce in open clusters across the Galactic disk is discussed within the context of s-process yields from asymptotic giant branch (AGB) stars, gigayear time delays in Ce enrichment of the interstellar medium, and the strong dependence of Ce nucleosynthesis on the metallicity of its AGB stellar sources. 

Serial crystallography of membrane proteins often employs high-viscosity injectors (HVIs) to deliver micrometre-sized crystals to the X-ray beam. Typically, the carrier medium is a lipidic cubic phase (LCP) media, which can also be used to nucleate and grow the crystals. However, despite the fact that the LCP is widely used with HVIs, the potential impact of the injection process on the LCP structure has not been reported and hence is not yet well understood. The self-assembled structure of the LCP can be affected by pressure, dehydration and temperature changes, all of which occur during continuous flow injection. These changes to the LCP structure may in turn impact the results of X-ray diffraction measurements from membrane protein crystals. To investigate the influence of HVIs on the structure of the LCP we conducted a study of the phase changes in monoolein/water and monoolein/buffer mixtures during continuous flow injection, at both atmospheric pressure and under vacuum. The reservoir pressure in the HVI was tracked to determine if there is any correlation with the phase behaviour of the LCP. The results indicated that, even though the reservoir pressure underwent (at times) significant variation, this did not appear to correlate with observed phase changes in the sample stream or correspond to shifts in the LCP lattice parameter. During vacuum injection, there was a three-way coexistence of the gyroid cubic phase, diamond cubic phase and lamellar phase. During injection at atmospheric pressure, the coexistence of a cubic phase and lamellar phase in the monoolein/water mixtures was also observed. The degree to which the lamellar phase is formed was found to be strongly dependent on the co-flowing gas conditions used to stabilize the LCP stream. A combination of laboratory-based optical polarization microscopy and simulation studies was used to investigate these observations. 

Abstract Single Particle Imaging (SPI) with intense coherent X-ray pulses from X-ray free-electron lasers (XFELs) has the potential to produce molecular structures without the need for crystallization or freezing. Here we present a dataset of 285,944 diffraction patterns from aerosolized Coliphage PR772 virus particles injected into the femtosecond X-ray pulses of the Linac Coherent Light Source (LCLS). Additional exposures with background information are also deposited. The diffraction data were collected at the Atomic, Molecular and Optical Science Instrument (AMO) of the LCLS in 4 experimental beam times during a period of four years. The photon energy was either 1.2 or 1.7 keV and the pulse energy was between 2 and 4 mJ in a focal spot of about 1.3μm x 1.7μm full width at half maximum (FWHM). The X-ray laser pulses captured the particles in random orientations. The data offer insight into aerosolised virus particles in the gas phase, contain information relevant to improving experimental parameters, and provide a basis for developing algorithms for image analysis and reconstruction.